Tag Archives: Catalysts

CO2-Free NH3

Ken-ichi Aika
Tokyo Institute of Technology, Japan

NH3 Fuel Conference, Los Angeles, September 20, 2016

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RELATED NH3 FUEL CONFERENCE PAPERS

2013: Ammonia as an Energy Carrier for Renewable Energy

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Ken-ichi Aika, Tokyo Institute of Technology
Learn more about the 2016 NH3 Fuel Conference

Research and Development of Ammonia-fueled SOFC Systems

Koichi Eguchi1*, Atthapon Srifa1, Takeou Okanishi1, Hiroki Muroyama1, Toshiaki Matsui1, Masashi Kishimoto1, Motohiro Saito1, Hiroshi Iwai1, Hideo Yoshida1, Masaki Saito2, Takeshi Koide2, Hiroyuki Iwai2, Shinsuke Suzuki2, Yosuke Takahashi2, Toshitaka Horiuchi3, Hayahide Yamasaki3, Shohei Matsumoto4, Shuji Yumoto4, Hidehito Kubo4, Jun Kawahara5, Akihiro Okabe5, Yuki Kikkawa6, Takenori Isomura6
1 Kyoto University; 2 Noritake; 3 Nippon Shokubai; 4 Toyota Industries; 5 Mitsui Chemical; 6 Tokuyama, Japan

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

Ammonia is a promising hydrogen carrier because of its high hydrogen density, low production cost, and ease in liquefaction and transport. Ammonia decomposes into nitrogen and hydrogen through a mildly endothermic process. The ammonia decomposition temperature is close to the operating conditions of solid oxide fuel cells (SOFCs). Therefore, the integration of these two devices is beneficial in terms of efficient heat and energy managements and will lead to the development of simplified generation systems. Continue reading

Applications of hydrogen permeable membranes in ammonia synthesis and decomposition

Sean-Thomas B. Lundin*, Thomas F. Fuerst, Jason C. Ganley, Colin A. Wolden, J. Douglas Way
Department of Chemical and Biological Engineering, Colorado School of Mines, USA

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

It is well known that ammonia is being considered as a method of storing hydrogen. Although some fuel cells are being developed that can use ammonia directly as a fuel source, many fuel cell technologies still require an outside cracker to revert ammonia back into hydrogen for efficient use. In this regard, hydrogen permeable membranes, such as Pd and its alloys, have been targeted as potential membrane reactors in which the ammonia is cracked while the hydrogen is simultaneously separated. Pd and its alloys are expensive, but offer potentially perfect hydrogen purity that is highly preferable for certain fuel cells susceptible to ammonia poisoning. Yet, cheaper metals, such as V, Nb and Ta, may offer a more affordable alternative while maintaining perfect hydrogen selectivity. The first part of this talk will involve our work on ammonia decomposition using both Pd-based membranes and the cheaper V, Ta or Nb metals. Continue reading

Developments in Electrochemical Ammonia Synthesis

Stephen Szymanski*, Wayne Gellett
Proton Energy Systems, USA

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

Proton Energy Systems, d/b/a Proton OnSite, is a technology and commercialization leader in the field of membrane based electrolysis. The company was founded on the vision of utilizing electrolysis technology for the capture and storage of energy in high value applications. Recently, the concept of storing electrical energy in the form of a carbon neutral liquid fuel, particularly ammonia, has been gaining traction within the research investment community. Continue reading

Ammonia Fuel Cell and Fuel Synthesis Using Protonic Ceramics

Chuancheng Duan, Jinahua Tong, Jason Ganley*, Ryan O’Hayre
Colorado School of Mines, USA

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

Proton-conducting ceramics synthesized with solid-state reactive sintering are employed as electrolytes for the synthesis of ammonia from hydrogen and nitrogen gases in electrolytic cells. Additionally, these cells function with excellent long-term stability and high efficiency when operated in galvanic (fuel cell) mode using ammonia fuel. Advances in electrolyte compositions and synthesis techniques are discussed alongside cell performance metrics. Continue reading

Cracking ammonia

Bill David*1,2, Josh Makepeace2, Hazel Hunter1 and Tom Wood1
1ISIS Facility, Rutherford Appleton Laboratory, UK
2Inorganic Chemistry Laboratory, University of Oxford, UK

13th Annual NH3 Fuel Conference, September 19, 2016

ABSTRACT

In this talk, I will discuss our latest research in developing novel ammonia cracking catalysts. While ammonia can be used directly as a fuel in high temperature fuel cells, internal combustion engines and gas turbine, the ability to crack ammonia affordably and effectively increases the range of possibilities for utilising ammonia as an energy vector. Continue reading

Student Laboratory Module: Kinetics of Ammonia Cracking

Jason Ganley, Colorado School of Mines
11th Annual NH3 Fuel Conference, September 23, 2014 Continue reading

A novel approach to ammonia decomposition

W I F David
ISIS Facility, Rutherford Appleton Laboratory
Inorganic Chemistry Laboratory, University of Oxford

11th Annual NH3 Fuel Conference, September 23, 2014 Continue reading

Research and development of NH3-fueled solid-state fuel cell systems

Hiroki Muroyama* (1), Jun Yang (1), Kaname Okura (1), Takeou Okanishi (1), Toshiaki Matsui (1), Motohiro Saito (2), Hiroshi Iwai (2), Hideo Yoshida(2), Koichi Eguchi (1)
(1) Department of Energy and Hydrocarbon Chemistry, and (2) Department of Aeronautics and Astronautics, Graduate School of Engineering, Kyoto University

11th Annual NH3 Fuel Conference, September 23, 2014 Continue reading