Fast-Ramping Reactor for CO2-Free NH3 Synthesis

Joseph Beach1*, Jonathan Kintner1, Adam Welch1, Jason Ganley2, Ryan O’Hayre2
[1] Starfire Energy; and [2] Colorado School of Mines, United States

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

Starfire Energy is developing a fast-ramping reactor for making CO2-free NH3 for fuel, energy storage, and agricultural applications. A fast-ramping reactor is desired to follow (a) variable electricity generation from CO2-free sources such wind and solar power plants or (b) variable availability from CO2-free baseload electricity generation such as nuclear or hydroelectric power plants. The reactor builds upon the Haber-Bosch process by (a) introducing a higher activity supported Ru catalyst (over 4.5 mmol g-1 h-1 at 1 atm and over 45 mmol g-1 h-1 at 10 atm) and (b) further enhancing the catalysis by applying an electric potential or electric field to the catalyst. The catalysts and processes are the subjects of PCT patent application PCT/US17/20201. The catalysts and processes have been characterized in a differential reactor and are being incorporated into a prototype reactor designed to produce 3 kg NH3 per day. The presentation will feature data from the differential reactor and prototype reactor testing and modeled cost of CO2-free NH3 at larger production scales.

Read the abstract at the AIChE website.

DOWNLOAD

Presentations may be made available to download after the conference.

LINKS

Starfire Energy
Ammonia Synthesis for Fuel, Energy Storage, and Agriculture Applications, ARPA-E OPEN program, 2015
Learn more about the NH3 Fuel Conference 2017

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