Tag Archives: Direct Ammonia Fuel Cell

Development of Catalytic Reactors and Solid Oxide Fuel Cells Systems for Utilization of Ammonia

Koichi Eguchi*, Kyoto University, Japan, Yosuke Takahashi, Noritake Co., Japan, Takahiro Matsuo, IHI Corporation, Japan, Hayahide Yamasaki, Nippon Shokubai Co., Japan, Hidehito Kubo, Toyota Industries, Japan, Akihiro Okabe, Mitsui Chemicals, Japan, Takenori Isomura, Tokuyama Corp., Japan

15th Annual NH3 Fuel Conference, Pittsburgh, PA, October 31, 2018
NH3 Energy+ Topical Conference at the AIChE Annual Meeting

ABSTRACT

Hydrogen is the primary fuel source for fuel cells. However, the low volume density and difficulty in storage and transportation are major obstacles for the practical utilization. Among various hydrogen carriers, ammonia is one of the promising candidates because of its high hydrogen density and boiling point and ease in liquefaction and transportation. The reaction temperature of ammonia cracking to nitrogen and hydrogen, being about 600°C or higher, is close to the operating temperature of solid oxide fuel cells (SOFCs). The integration of these two devices is beneficial in terms of heat and energy managements and will lead to the development of simplified power generation systems.

Several catalyst materials, i.e., cracking, autothermal cracking, and combustion of ammonia have been investigated and used for the SOFC systems. A demonstration of the stack-level ammonia-fueled SOFC systems is an important step for the actual utilization of ammonia-fueled SOFCs. In this study, 200 W class and 1 kW class SOFC stacks were applied for ammonia fueled generation systems. Continue reading

Direct Ammonia Fuel Cell Utilizing an OH- Ion Conducting Membrane Electrolyte

Yushan Yan1, Shimshon Gottesfeld1,2*
[1] University of Delaware; and [2] FC Consulting Ltd, United States

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

We describe the techno-economic background and the R&D work scheduled for the ARPA-E project “Direct Ammonia Fuel Cells (DAFCs) for Transportation Applications,” which is about to start under the REFUEL program. The project is led by Shimshon Gottesfeld & Yushan Yan, University of Delaware, Jia Wang & Radoslav Adzic, Brookhaven National Laboratory, Chulsung Bae, Rensselaer Polytechnic Institute, and Bamdad Bahar, Xergy Inc. The multidisciplinary R&D work scheduled will cover the fields of advanced membrane and electrocatalyst development, MEA development and fabrication, and stack engineering. The latter two activities will be supported by work at POCellTech, with Miles Page as lead.

The Project Vision is creation of a high power density, direct ammonia fuel cell suitable for transportation applications, using a hydroxide exchange membrane electrolyte and operating the cell near 100°C. A practical ammonia fuel cell should enable use of the lowest cost, carbon-neutral liquid fuel for clean, long-range transportation. Continue reading

Development of Materials and Systems for Ammonia-Fueled Solid Oxide Fuel Cells

Koichi Eguchi1*, Yosuke Takahashi2, Hayahide Yamasaki3, Hidehito Kubo4, Akihiro Okabe5, Takenori Isomura6, Takahiro Matsuo7
[1] Kyoto University; [2] Noritake; [3] Nippon Shokubai; [4] Toyota Industries; [5] Mitsui Chemicals; [6] Tokuyama; and [7] IHI Corporation, Japan

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

Hydrogen is the primary fuel source for fuel cells. However, the low volume density and difficulty in storage and transportation are major obstacles for the practical utilization. On-site generation of hydrogen from its carrier is an effective method for the fuel supply. Among various hydrogen carriers, ammonia is one of the promising candidates. Ammonia has high hydrogen density. The boiling point of ammonia is relatively high, leading to the ease in liquefaction and transportation. Hydrogen can be produced from ammonia with a mildly endothermic process. The reaction temperature of ammonia cracking is about 600˚C or higher which is close to the operating temperature of solid oxide fuel cells (SOFCs). The integration of these two devices is beneficial in terms of heat and energy managements and will lead to the development of simplified power generation systems. In this presentation, three types of ammonia-fueled SOFC systems have been investigated. Continue reading