Tag Archives: NH3 combustion

Evaluation of the Cement Clinker Fired in the Combustion Furnace of Heavy-Oil and NH3

Hiroki Kujiraoka*, Tatsurou Izumi, Yuya Yoshizuru, Takeshi Suemasu, Makoto Ueda, Toyoaki Niki, Takayasu Itou, UBE Industries, Japan; Ryuichi Murai, Fumiteru Akamatsu, Osaka University, Japan

15th Annual NH3 Fuel Conference, Pittsburgh, PA, October 31, 2018
NH3 Energy+ Topical Conference at the AIChE Annual Meeting

ABSTRACT

In recent years, global warming caused by an increase in CO2 emission released by combustion of fossil fuel has become a big problem. To realize a low-carbon society, active use of renewable energy and promotion of hydrogen energy are necessary. We are participating in “SIP (Strategic Innovation Promotion Program) energy carriers”, developing technology to replace 30% fossil fuel with ammonia (NH3) on the calorie basis. Assuming that NH3 is used as a thermal energy for a cement kiln, we conducted the following two basic experiments.

First, we fired the clinker in the atmosphere-controlled electric furnace, calculated the reaction rate of CaO which is the main oxide in clinker by Arrhenius type kinetic model. As a result, it was found that the reaction rate of clinker was not influenced by the atmosphere conditions and was dominated by the temperature conditions.

Next, we fired the clinker in the 10 kW furnace under only heavy-oil combustion and mixed combustion of heavy-oil and NH3, identified mineral composition by X-ray diffraction (XRD)/Rietveld analysis, carried out the strength test for cement was made from the clinker. As a result, it was confirmed there was no difference in mineral composition and strength of clinker. Continue reading

Demonstration of CO2-Free Ammonia Synthesis Using Renewable Energy-Generated Hydrogen

Mototaka Kai*, Yasushi Fujimura, Takayoshi Fujimoto, JGC Corporation, Japan; Hideyuki Takagi, Yuichi Manaka, National Institute of Advanced Industrial Science and Technology (AIST), Japan; Tetsuya Nanba, Fukushima Renewable Energy Institute, AIST (FREA), Japan

15th Annual NH3 Fuel Conference, Pittsburgh, PA, October 31, 2018
NH3 Energy+ Topical Conference at the AIChE Annual Meeting

ABSTRACT

In Japan, the government funding project SIP, Strategic Innovation Promotion Program, supports the research, development and demonstration of “Energy Carriers”. The concept of the “Energy Carriers” value chain is to produce hydrogen energy carriers overseas from fossil resources using CCS or renewable energy, and transport it to Japan for utilization as clean energy. The purpose of the program is to help realize a low-carbon society in Japan by using hydrogen. Among energy carriers, ammonia is the one of the most promising carriers, because of the ease of transportation as a liquid, higher hydrogen density, and proven technologies for commercial and industrial scale, not only for production, storage, and transportation, but also its utilization in chemical plants and DeNOx units for electric power plants.

Under the theme of “Development of ammonia synthesis from CO2-free hydrogen” of SIP ”Energy Carriers”, JGC is developing the advanced ammonia synthesis process using renewable energy, such as Photovoltaic and Wind Turbine Power Generation, to be able to produce “Green” ammonia, aiming to contribute to a low-carbon society. Also, utilizing the catalysts developed by the National Institute of Advanced Industrial Science and Technology (hereinafter “AIST”), National Institute of Technology Numazu College, and JGC C&C, AIST and JGC designed and constructed an ammonia synthesis demonstration plant in FREA, the Fukushima Renewable Energy Institute, AIST by the end of fiscal year 2017. From April 2018, the plant started operation to evaluate the performance of the developed catalysts and acquire the engineering data for scaling up in the future.

In this paper, we would like to explain the details of the ammonia synthesis demonstration plant in FREA, such as process flow, plant operation conditions, its capacity, and the status of plant operation. Continue reading

Test Results of the Ammonia Mixed Combustion at Mizushima Power Station Unit No.2 and Related Patent Applications

Hiroaki Tanigawa, Chugoku Electric Power Company, Japan

15th Annual NH3 Fuel Conference, Pittsburgh, PA, October 31, 2018
NH3 Energy+ Topical Conference at the AIChE Annual Meeting

ABSTRACT

At the Mizushima Power Station Unit No.2 (Coal-fired, Location: Kurashiki, Okayama Prefecture, rated output: 156,000 kW), the Chugoku Electric Power Company conducted the ammonia mixed-combustion test from July 3 to 9, 2017, in order to reduce the environmental burden of coal-fired power stations. We compile the test results and report it to Japan Science and Technology Agency (JST), and we are pleased to inform you today that we applied for patents on the findings obtained in this examination. Continue reading

Ship Operation Using LPG and Ammonia As Fuel on MAN B&W Dual Fuel ME-LGIP Engines

René Sejer Laursen, MAN Diesel & Turbo, Denmark

15th Annual NH3 Fuel Conference, Pittsburgh, PA, October 31, 2018
NH3 Energy+ Topical Conference at the AIChE Annual Meeting

ABSTRACT

LPG has been used as fuel in the car industry for many years and now, with Exmar and Statoil’s orders for ocean-going ships fitted with the dual fuel ME-LGIP engine, LPG will be used on marine engines as well. The new engine series is currently being developed to match all types of bigger merchant ships. This order was made in consequence of the new 2020 0.5% sulphur fuel cap, but this step forward has not stopped the discussion and interest in lowering CO2, NOx, SOx and particulate emissions even further. On the contrary, it has actually been further fuelled by the latest IMO meeting targeting a 50%-cut in greenhouse gas emissions from ocean-going shipping by 2050 compared with 2008.

Because the world fleet has increased since 2008, and thus CO2 emissions as well, it has been realised that this goal cannot be met without the use of carbon-free fuels. In shipping, 30 years corresponds to the lifetime of a ship, and owners will therefore soon need to consider this when they select the propulsion solution for their next ship. And as marine engine maker, MAN Diesel & Turbo needs to be fully prepared.

Using LPG as fuel on the two-stroke ME-LGIP engine offers similar emission benefits as with LNG, which reduces emissions significantly compared with MDO. Therefore, there are very good environmental reasons for using this fuel in coastal areas, on inland waterways and on deep sea. The LGIP engine solution system can also be applied on engine sizes from 5 to 85 MW, which are suitable for tankers, bulk carriers, container vessels, etc.

It is expected that the need to reduce CO2 emissions will fuel a continued growth in shipping. And because sea transportation has proven to be less CO2 polluting than both trucks and trains using fossil fuels this trend is expected to continue. Furthermore, the world population is increasing as well, and this is expected to increase the shipping fleet. So significant CO2 reduction is mandatory in shipping, and this can be improved by using carbon-free fuels such as bio-LPG/LNG, and the so-called “electric fuels”, etc. There are also plans to remove CO2 from methane to produce carbon-free ammonia, but in order to be fully carbon free, the CO2 should be removed by, for example, injecting it into the seabed. MAN Diesel & Turbo already have dual fuel engines in our engine programme that can operate on LNG and methanol, but ammonia as a fuel has not yet been investigated for use on two-stroke engines.

This paper describes the technology behind the ME-LGIP dual fuel MAN B&W two-stroke engines, using LPG as fuel, and its associated LPG tank and fuel supply systems. The engine requires a gas supply pressure of 50-bar and controlled to a temperature of 45°C. At this temperature and pressure, the LPG is liquid, and different fuel supply solutions are available for generating this pressure for the liquid. Hence, the ME-LGIP for LPG will use liquid gas for injection, contrary to the ME-GI for LNG, where the methane is injected in gaseous form. All the way from tank to engine, the LPG remain in liquid phase, and conventional pumps can be used to generate the pressure. Furthermore, we have lately found that this engine technology, with minor modification, can also be used to burn ammonia, so the paper will also describe the modification needed in order to build an engine that is able to burn LPG as well as ammonia.

Safety is a concern when both LPG and ammonia is used as fuel on an engine located in an engine room. This is because LPG in gaseous form, contrary to methane, is heavier than air and will drop in case of leakage, and because ammonia in a gaseous form is toxic. This safety has been analysed, and our safety considerations and precautions will be described in details. Continue reading

Ammonia-Hydrogen Power for Combustion Engines

Agustin Valera-Medina*, Phil Bowen, Daniel Pugh, Cardiff University, UK

15th Annual NH3 Fuel Conference, Pittsburgh, PA, October 31, 2018
NH3 Energy+ Topical Conference at the AIChE Annual Meeting

ABSTRACT

Ammonia blends can potentially become a breakthrough chemical for power generation, cooling storage and distribution of energy. Gas turbines and internal combustion engines are potential candidates for the use of the resource in an efficient way that will enable commissioning of combined cycles to power communities around Europe and around the world while serving as sources of heat and chemical storage. Therefore, development of these systems will bring to the market a safer, zero carbon fuel that can be used for multiple purposes, thus decentralizing power generation and increasing sustainability in the communities of the future whilst positioning the developing and manufacturing companies as global leaders of a new generation of energy devices.

This work summarises results from various analytical, numerical and experimental campaigns carried out at Cardiff University, Wales, UK. Each of these is related to combustion of ammonia blended with hydrogen at different concentrations and conditions. Continue reading

NH3 / N2 / O2 Non-Premixed Flame in a 10 kW Experimental Furnace – Characteristics of Radiative Heat Transfer

Ryuichi Murai1*, Ryohei Omori1, Ryuki Kano1, Yuji Tada1, Hidetaka Higashino1, Noriaki Nakatsuka1, Jun Hayashi1, Fumiteru Akamatsu1, Kimio Iino2, Yasuyuki Yamamoto2, Yoshiyuki Hagiwara2
[1] Osaka University; and [2] Taiyo Nippon Sanso, Japan

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

There are severe issues on increasing amount of carbon dioxide (CO2) emission in the world. Many studies are devoted on alternative fuels. One of superior candidates is the utilization of hydrogen energy which can realize a low-carbon and hydrogen-based society. Ammonia might play an important role which is zero emission of CO2, and is useful for hydrogen energy carrier as a clean energy. Additionally, ammonia is an easily-liquefiable fuel with pressure of about 0.86 MPa and temperature of 293 K. Commercially, ammonia is produced in large quantity by the Haber–Bosch process. It is also to be produced by using catalyst with renewable energy sources, such as wind energy and solar energy. Continue reading

Efficient and Clean Combustion of Ammonia-Hydrogen-Air Mixtures

Hadi Nozari1, Arif Karabeyoğlu1,2
[1] Koç University, Istanbul, Turkey; [2] Space Propulsion Group, Palo Alto CA, United States

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

Based on its well-known merits ammonia has been gaining special attention as a potential renewable energy carrier which can be replaced in power generation systems. Considering its low flame speed and its potential for producing fuel NOx as the main challenges of combusting ammonia, flame stability, combustion efficiency, and NOx formation are experimentally investigated. Focus is on premixed ammonia-hydrogen-air flames with high mixture fractions of ammonia (60-90% by volume) under standard temperature and pressure conditions. Continue reading

Effects of the Thickness of the Burner Rim, the Velocities of Fuel and Air on Extinction Limit of Ammonia Coaxial Jet Diffusion Flame

Yohei Ishikawa1, Jun Hayashi1*, Hiroyuki Takeishi1, Takahiro Okanami1, Kimio Iino1, Fumiteru Akamatsu1, Yasuyuki Yamamoto2, Yoshiyuki Hagiwara2
[1] Osaka University; and [2] Taiyo Nippon Sanso, Japan

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

Ammonia is regarded as one of the alternative fuels because CO2 doesn’t emit during the combustion process of ammonia. Ammonia also has advantages in storage and transportation. In addition, ammonia has a potential to be a “hydrogen carrier” because of high amount of hydrogen content. However, there are several combustion related problems such as the low flammability, the low radiative power and the high NOx formation. To use ammonia as a fuel, therefore, it is necessary to understand the fundamental phenomena of the combustibility of the ammonia such as laminar burning velocity, strength of the radiation and extinction limit. Since a coaxial jet diffusion flame is commonly used on the industrial furnaces, the extinction limit of ammonia coaxial jet diffusion flame is important to know for developing ammonia-flamed furnaces. Continue reading

Effect of Water on the Auto-Ignition of a Non-Carbon Nitrogen-Based Monofuel

Bar Mosevitzky*, Rotem Azoulay, Lilach Naamat, Gennady E. Shter, Gideon S. Grader
Technion – Israel Institute of Technology, Israel

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

The fluctuating nature of renewable energy sources is becoming a limiting factor in their widespread utilization. Energy storage solutions must be developed to overcome this issue. Chemical fuels are considered to be a promising solution to this problem. We are studying the implementation of nitrogen-based fuels for this purpose. An aqueous solution of ammonium nitrate and ammonium hydroxide (AAN) is suggested as a carbon-free nitrogen-based synthetic monofuel. This solution may serve as a renewable nitrogen-based synthetic hydrogen carrier since it is safe to store, transport and utilize. Since ammonium hydroxide (AH) and ammonium nitrate (AN) act as reducer and net oxidizer, they can combust without the need for an external oxidizer (i.e. O2/Air). The amount of water in this solution greatly affects the saturation point and hence the sensitivity to re-crystallization at low temperatures which in turn affects the storage conditions. Thus, the effect of AAN’s water content on its thermal autoignition must be investigated. Continue reading

Development of New Combustion Strategy for Internal Combustion Engine Fueled By Pure Ammonia

Donggeun Lee*, Hyungeun Min, Hyunho Park, Han Ho Song
Seoul National University, South Korea

NH3 Fuel Conference, Minneapolis, November 1, 2017
AIChE Annual Meeting, Topical Conference: NH3 Energy+

ABSTRACT

Ammonia is considered as a promising hydrogen-carrier with good storability and transportability, which, then, can be used as a carbon-free fuel as needed. However, once the ammonia is produced from the regenerative sources, it is essential to develop the energy conversion device of the chemical energy stored in ammonia into some other useful forms, e.g. electricity. Among various candidates, we focus on an internal combustion engine as energy conversion device which can be applied on automobile, power plant and etc. and can use ammonia as fuel only by simple modification. There have been many studies on the use of ammonia as an engine fuel, but rather poor combustion characteristics of ammonia for conventional engine combustion techniques was seen as difficult to overcome and nearly all the researchers compromised by using additional fuels which combusted better than ammonia for their purposes. Continue reading