Tag Archives: Electrochemical Synthesis

Japan – a future market for Australian solar ammonia

Keith Lovegrove
ITP Thermal Pty Ltd, Australia

NH3 Fuel Conference, Los Angeles, September 20, 2016

ABSTRACT

Japan and Australia are intimately linked in energy trade. Australia counts energy exports as a major source of foreign exchange income and Japan, which uses nearly 4 times the primary energy as Australia, imports nearly all of it. Approximately 40% of Australia’s coal exports are bought by Japan and were worth $AUD15.4 billion in 2012-13. Over 70% of Australia’s LNG exports went to Japan in the same period and earned over $AUD12billion. Future energy supply is high on the agenda for Japan. Currently 43% of its primary energy is in the form of imported oil mostly from the Middle East. The cost of this together with energy security concerns is a major driver for change. Post the Fukushima Nuclear disaster, the previous 8% contribution from Nuclear dropped to zero and there is much opposition to reinstating it. Japan still has a strong policy agenda to reduce Greenhouse Gas Emissions.

One of the identified routes to a cleaner energy future is the wider use of hydrogen as a fuel in both the transport and power generation sectors. There are a range of technology approaches that allow solar technologies to produce transportable alternative fuels that could form the basis for a future clean energy trade with Japan. If energy is transported as an energy dense liquid in conventional tanker ships, then the effective efficiency of transport over distances of 6000km (Australia to Japan) is greater than 98%. Three options for importing hydrogen fuel into Japan are under serious consideration; cryogenic liquid hydrogen, reversible hydrogenation of toluene, and conversion of hydrogen to ammonia. Ammonia is increasingly considered as the favourable path. It offers higher energy density, leverages an existing global industry and has the potential for direct combustion in combined cycle power plants and heavy transport. Considering Australia’s vast untapped solar resource together with the existing energy trade history plus a history of upstream investments by Japanese companies in Australian Energy developments, suggests the two countries are ideal partners in a future solar fuels trade.

DOWNLOAD

Download this presentation here [PDF, 3.8MB]

RELATED NH3 FUEL CONFERENCE PAPERS

2008: Ammonia Production and Baseload Solar Power [PDF]

LINKS

Keith Lovegrove, ITP
Learn more about the 2016 NH3 Fuel Conference

Decentralised ammonia production in the Netherlands

Hans Vrijenhoef
Proton Ventures, The Netherlands

NH3 Fuel Conference, Los Angeles, September 20, 2016

ABSTRACT

Our presentation will summarize the results of two government funded research projects Proton carried out over the last year. Continue reading

The Investment Case for Sustainable Ammonia Synthesis Technologies

Trevor Brown
AmmoniaIndustry.com, USA

NH3 Fuel Conference, Los Angeles, September 20, 2016

ABSTRACT

For 100 years, we have made ammonia with the Haber-Bosch process, almost always using a fossil fuel feedstock. Recently, though, government policy, academic innovation, commercial opportunity, and human morality have combined to spur the development of new, “green” ammonia manufacturing processes: sustainable, low-carbon technologies.

These new synthesis methods augur a future in which, instead of the single, over-riding drive toward the economies of scale associated with Haber-Bosch, an array of different feedstocks, uses, and business models will support a multiplicity of competing technologies serving multiple markets. Continue reading

Electro-Synthesis of Ammonia for Grid Scale Energy Storage

Shekar Balagopal1*, Matt Robbins1, Alvare Javier1, Marc Flinders1, Joshua Johnston1, Fernando Garzon2, Jamie Gomez2, Cortney Kreller3, Rangachary Mukundan3, Yu Seung Kim3
1 Ceramatec Inc, 2 University of New Mexico, and 3 Los Alamos National Laboratory, USA

NH3 Fuel Conference, Los Angeles, September 20, 2016

ABSTRACT

Ceramatec Inc., in partnership with its partners, will develop a lower temperature and higher efficiency membrane process to synthesize ammonia for energy storage. Continue reading

Ammonia for Green Energy Storage and Beyond

Ian Wilkinson
Siemens Corporate Technology, UK

NH3 Fuel Conference, Los Angeles, September 20, 2016

ABSTRACT

Siemens is participating in an all electric ammonia synthesis and energy storage system demonstration programme at Rutherford Appleton Laboratory, near Oxford. The demonstrator, which will run until December 2017, is supported by Innovate UK. Collaborators include the University of Oxford, Cardiff University and the Science & Technology Facilities Council. Continue reading

Applications of hydrogen permeable membranes in ammonia synthesis and decomposition

Sean-Thomas B. Lundin*, Thomas F. Fuerst, Jason C. Ganley, Colin A. Wolden, J. Douglas Way
Department of Chemical and Biological Engineering, Colorado School of Mines, USA

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

It is well known that ammonia is being considered as a method of storing hydrogen. Although some fuel cells are being developed that can use ammonia directly as a fuel source, many fuel cell technologies still require an outside cracker to revert ammonia back into hydrogen for efficient use. In this regard, hydrogen permeable membranes, such as Pd and its alloys, have been targeted as potential membrane reactors in which the ammonia is cracked while the hydrogen is simultaneously separated. Pd and its alloys are expensive, but offer potentially perfect hydrogen purity that is highly preferable for certain fuel cells susceptible to ammonia poisoning. Yet, cheaper metals, such as V, Nb and Ta, may offer a more affordable alternative while maintaining perfect hydrogen selectivity. The first part of this talk will involve our work on ammonia decomposition using both Pd-based membranes and the cheaper V, Ta or Nb metals. Continue reading

Developments in Electrochemical Ammonia Synthesis

Stephen Szymanski*, Wayne Gellett
Proton Energy Systems, USA

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

Proton Energy Systems, d/b/a Proton OnSite, is a technology and commercialization leader in the field of membrane based electrolysis. The company was founded on the vision of utilizing electrolysis technology for the capture and storage of energy in high value applications. Recently, the concept of storing electrical energy in the form of a carbon neutral liquid fuel, particularly ammonia, has been gaining traction within the research investment community. Continue reading

Overview of the KIER’s Electrochemical Ammonia Synthesis – Present State and Perspective

Chung-Yul Yoo*, Hyung Chul Yoon*, Dae Sik Yun, Jong-Nam Kim
Korea Institute of Energy Research (KIER), Republic of Korea

NH3 Fuel Conference, Los Angeles, September 20, 2016

ABSTRACT

Ammonia has a potential as a carbon-free energy carrier since it contains 17.6wt% of hydrogen and can be easily stored and transported safely and efficiently. The state-of-the-art industrial process for ammonia production is the Haber-Bosch process. Although high temperature (450–500 °C) and pressure (150–300 bar) are used to dissociate triple-bonded nitrogen and to maximize the ammonia formation, the efficiency of the Haber–Bosch process is limited to 10–15%. Moreover, the process accompanies high greenhouse gases emission since hydrogen is produced from natural gas. In order to overcome the drawbacks of the Haber-Bosch process, the electrochemical ammonia synthesis has been developed as an alternative process. Continue reading

Ammonia Fuel Cell and Fuel Synthesis Using Protonic Ceramics

Chuancheng Duan, Jinahua Tong, Jason Ganley*, Ryan O’Hayre
Colorado School of Mines, USA

NH3 Fuel Conference, Los Angeles, September 19, 2016

ABSTRACT

Proton-conducting ceramics synthesized with solid-state reactive sintering are employed as electrolytes for the synthesis of ammonia from hydrogen and nitrogen gases in electrolytic cells. Additionally, these cells function with excellent long-term stability and high efficiency when operated in galvanic (fuel cell) mode using ammonia fuel. Advances in electrolyte compositions and synthesis techniques are discussed alongside cell performance metrics. Continue reading

Progress in the Electrochemical Synthesis of Ammonia

V. Kyriakou, I. Garagounis, E. Vasileiou, A. Vourros, M. Stoukides
Department of Chemical Engineering, Aristotle University, Greece
Chemical Processes & Energy Resources Institute, CERTH, Greece
Presenter: W. Grover Coors

13th Annual NH3 Fuel Conference, September 19, 2016

ABSTRACT

Ammonia is one of the most important and widely produced chemicals worldwide with a key role in the growth of human population. Nowadays, the main route for ammonia synthesis is the Haber-Bosch process, developed one century ago. In this process, Fe-based catalysts are usually employed at temperatures between 400 and 500°C and pressures between 130 and 170 bar.

As opposed to the industrial process, in nature, plants and bacteria have been producing ammonia for millions of years at mild conditions. Atmospheric nitrogen is reduced by solvated protons on the FeMo cofactor of the metalloenzyme nitrogenase. The natural method of nitrogen fixation has motivated several research groups to explore the electrochemical synthesis of ammonia at ambient pressure. Continue reading